try these steps machan
go to Tools-> Account Settings.
In the new account settings, select Internet Email which connects to email account using POP or IMAP access.
In the next step, add your account details like email ID, name, password and server information.
POP server: pop3.live.com (Port 995)
POP SSL required? Yes
User name: Your Windows Live ID, for example
[email protected]
Password: The password you usually use to sign in to Hotmail or Windows Live
SMTP server: smtp.live.com (Port 25 or 587)
Authentication required? Yes (this matches your POP username and password)
TLS/SSL required? Yes
Click on More settings button and this will open advanced settings. In the Outgoing server tab, select the box against “My outgoing server (SMTP) requires authentication”.
Next select the advanced tab and enter the outgoing and incoming server ports as mentioned above.
Once you have entered all the settings, Outlook will connect to Hotmail server and fetch all you email using POP3 access.